Preheat Oven and Line Tin:
Preheat your oven to 350°F (175°C). Insert paper liners into a muffin tin.Whisk Dry Ingredients Together:
In a large mixing bowl, combine flour, sugar, cocoa powder, baking powder, and salt with a whisk.Mix Wet Ingredients Uniformly:
In another bowl, beat eggs, milk, oil, vanilla extract, and espresso together until uniform.Fold Wet into Dry Gently:
Add the wet mixture to the dry ingredients and fold gently until barely combined. Avoid overworking the batter for a light texture.Melt Chocolate and Mix Chips:
Melt the filling chocolate in a saucepan or microwave, then mix in the chocolate chips.Fill Cups Half Full:
Spoon batter into each muffin cup until roughly half full.Add Chocolate-Espresso Center:
Drop 1 teaspoon of the chocolate-espresso blend into the center of each portion.Cover with Remaining Batter:
Cover with the remaining batter, filling each cup to about three-quarters full.Bake Until Firm and Browned:
Bake for 18-20 minutes, until the tops are firm and lightly browned.Cool Muffins on Rack:
Allow muffins to rest in the pan for several minutes, then move them to a wire rack to finish cooling.